ESI-FTICR-MS Molecular Characterization of DOM Degradation under Warming in Tundra Soils from Utqiagvik (Barrow), Alaska

DOI: https://doi.org/10.5440/1410297
NGEE Arctic Record ID: NGA135
Data Version: 1.0
Abstract

This dataset provides the results of warming incubation of Arctic soils from trough areas of a high-center polygon at the Barrow Environmental Observatory (BEO) in northern Alaska, United States. The organic-rich soil (8-20 cm below ground surface) and the mineral-rich soil (22-45 cm below surface) were separated, and the thawed and homogenized subsamples from each soil were incubated at -2 degrees C or 8 degrees C for 122 days under anoxic conditions (headspace filled with N2). The extracted DOM from soil samples were analyzed by Fourier transform ion cyclotron resonance mass spectrometry coupled with electrospray ionization (ESI-FTICR-MS). Reported analytes include soil water content, dissolved organic carbon, total organic carbon, MS peaks' m/z and intensities, and elemental composition of identified molecular formulas. This dataset includes five csv files and one pdf file.

The Next-Generation Ecosystem Experiments: Arctic (NGEE Arctic), was a research effort to reduce uncertainty in Earth System Models by developing a predictive understanding of carbon-rich Arctic ecosystems and feedbacks to climate. NGEE Arctic was supported by the Department of Energy's Office of Biological and Environmental Research.

The NGEE Arctic project had two field research sites: 1) located within the Arctic polygonal tundra coastal region on the Barrow Environmental Observatory (BEO) and the North Slope near Utqiagvik (Barrow), Alaska and 2) multiple areas on the discontinuous permafrost region of the Seward Peninsula north of Nome, Alaska.

Through observations, experiments, and synthesis with existing datasets, NGEE Arctic provided an enhanced knowledge base for multi-scale modeling and contributed to improved process representation at global pan-Arctic scales within the Department of Energy's Earth system Model (the Energy Exascale Earth System Model, or E3SM), and specifically within the E3SM Land Model component (ELM).

Authors
Hongmei Chen (chenh2@ornl.gov) 0000-0003-2460-838X
Ziming Yang (zimingyang@oakland.edu) 0000-0003-0312-8408
Rosalie Chu ()
Nikola Tolic ()
Liyuan Liang (liangl@ornl.gov) 0000-0003-1338-0324
David Graham (grahamde@ornl.gov) 0000-0001-8968-7344
Stan Wullschleger (wullschlegsd@ornl.gov) 0000-0002-9869-0446
Baohua Gu (gub1@ornl.gov) 0000-0002-7299-2956
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Dataset Citation
Hongmei Chen, Ziming Yang, Rosalie Chu, Nikola Tolic, Liyuan Liang, David Graham, Stan Wullschleger, Baohua Gu. 2018. ESI-FTICR-MS Molecular Characterization of DOM Degradation under Warming in Tundra Soils from Utqiagvik (Barrow), Alaska. Next Generation Ecosystem Experiments Arctic Data Collection, Oak Ridge National Laboratory, U.S. Department of Energy, Oak Ridge, Tennessee, USA. Dataset accessed on [INSERT_DATE] at https://doi.org/10.5440/1410297.
Dates
2012-04-16 - 2012-04-16
Geographic Location
NGEE Arctic Utqiagvik (Barrow), Alaska
North71.35
South71.2
East-156.4
West-156.7
Place Keywords:
Barrow, Alaska | Intensive Site 1 | Area B | North Slope, Alaska | Utqiagvik, Alaska
Subject Keywords:
Soil characteristics | ORGANIC MATTER | ORGANIC CARBON | ELEMENTS |
GCMD Keywords
N/A
Methodology
In brief, frozen soil core samples were obtained from trough areas of a high-center polygon at the Barrow Environmental Observatory (BEO) in northern Alaska, United States. The organic-rich soil (8-20 cm below ground surface) and the mineral-rich soil (22-45 cm below surface) were separated, and the thawed and homogenized subsamples from each soil were incubated at minus 2 degrees C or 8 degrees C for 122 days under anoxic conditions (headspace filled with N2). At pre-determined time intervals, an aliquot of the wet soil (1-2 g) was taken and immediately stored in 20 oC freezer until DOM extraction. Prior to FTICR-MS analysis, soil samples were defrosted at room temperature and then equilibrated with 10 mM NH4HCO3 (pH ~ 7.3) solution for 6 h. Samples were centrifuged for 15 min at 6500g, and the supernatants (containing DOM) were collected and filtered through 0.45-um Nylon membrane filters before analysis. The extracted DOM was analyzed using a 15T FTICR-MS (Bruker SolariX, Billerica, MA) fitted with a standard electrospray ionization (ESI) interface.
Related References
N/A
Related Identifiers
N/A
Metadata Contact
Contact information for the individual or organization that is knowledgeable about the data.
Person: Baohua Gu
Organization: Oak Ridge National Laboratory
Email: gub1@ornl.gov
Point of Contact
Contact information for the individual or organization that is knowledgeable about the data.
Person: Baohua Gu
Organization: Oak Ridge National Laboratory
Email: gub1@ornl.gov
Dataset Usage Rights
Public Datasets

This work is licensed under the Creative Commons Attribution 4.0 International License. To view a copy of this license, visit https://creativecommons.org/licenses/by/4.0.

See the NGEE Arctic Data Policies for more details https://ngee-arctic.ornl.gov/data-policies.

Distribution Point of Contact
Contact: Data Center Support
Organization: Next-Generation Ecosystem Experiments (NGEE) Arctic Project, Oak Ridge National Laboratory
Email: support@ngee-arctic.ornl.gov